Aryl Amination Using Soluble Weak Base Enabled by a Water-Assisted Mechanism

Lau, S.; Yu, P.; Chen, L.; Madsen-Duggan, C. B.; Williams, M. J.; Carrow, B. P.

J. Am. Chem. Soc. 2020,142, 20030-20039. DOI: 10.1021/jacs.0c09275

Base-Assisted C–H Bond Cleavage in Cross-Coupling: Recent Insights into Mechanism, Speciation, and Cooperativity

Carrow, B. P.; Sampson, J.; Wang, L.

Israel J. Chem. 2019, 60, 230–258.
2019 Wolf Prize special issue

Oligothiophene Synthesis by a General
C–H Activation Mechanism: Electrophilic Concerted Metalation-Deprotonation (eCMD)

Wang, L.; Carrow, B. P.

ACS Catal. 2019, 9, 6821–6836. DOI: 10.1021/acscatal.9b01195

A Diverted Aerobic Heck Reaction Enables Selective 1,3-Diene and 1,3,5-Triene Synthesis through C–C Bond Scission

McAlpine, N. J.; Wang, L.; Carrow, B. P.

J. Am. Chem. Soc. 2018 140, 13634–13639.

Highlighted in Organic Chemistry Portal (link)

Electron-Rich Metal Cations Enable Synthesis of High Molecular Weight, Linear Functional Polyethylenes

Zhang, W.; Waddell, P. M.; Tiedemann, M. A.; Padilla, C. E.; Mei, J.; Chen, L.; Carrow, B. P.

J. Am. Chem. Soc. 2018, 140, 8841–8850.

An ‘On-Cycle’ Precatalyst Enables Room Temperature Polyfluoroarylation Using Sensitive Boronic Acids

Chen, L.; Francis, H.; Carrow, B. P.

ACS Catal. 2018, 4, 2989–2994.

Methylene-Bridged Bisphosphine Monoxide Ligands for Palladium-Catalyzed Copolymerization of Ethylene and Polar Monomers

Mitsushige, Y.; Yasuda, H.; Carrow, B. P.; Ito, S.; Kobayashi, M.; Tayano, T.; Watanabe, Y.; Okuno, Y.; Hayashi, S.; Kuroda, J.; Okumura, Y.; Nozaki, K.

ACS Macro Lett. 2018 7, 305–311.

C–H Alkenylation of Heteroarenes: Mechanism, Rate, and Selectivity Changes Enabled by Thioether Ligands

Gorsline, B. J.; Wang, L.; Ren, P.; Carrow, B. P.

J. Am. Chem. Soc. 2017, 139, 9605–9614.

’Cationic’ Suzuki-Miyaura Coupling with Acutely Base-Sensitive Boronic Acids

Chen, L.; Sanchez, D. R.; Zhang, B. Carrow, B. P.

J. Am. Chem. Soc. 2017, 139, 12418–12421.

Tri(1-adamantyl)phosphine: Exceptional Catalytic Effects Enabled by the Synergy of Chemical Stability, Donicity, and Polarizability

Carrow, B.P.; Chen, L.

Synlett 2017, 28 (03), 280–288.

Reactions of 2-Methyltetrahydropyran on Silica-Supported Nickel Phosphide in Comparison with 2-Methyltetrahydrofuran

Bui, P. P.; Oyama, S. T.; Takagaki, A.; Carrow, B. P.; Nozaki, K.

ACS Catal. 2016, 6 (7), 4549–4558.

Tri(1-adamantyl)phosphine: Expanding the Boundary of Electron-Releasing Character Available to Organophosphorus Compounds

Chen, L.; Ren, P.; Carrow, B.P.

J. Am. Chem. Soc. 2016, 138 (20), 6392–6395.

Ligand-controlled insertion regioselectivity accelerates copolymerisation of ethylene with methyl acrylate by cationic bisphosphine monoxide-palladium catalysts

Mitsushige, Y.; Carrow, B. P.; Ito, S.; Nozaki, K.

Chem. Sci. 2016, 7 (1), 737-744.

Transition-Metal-Catalyzed Functional Polyolefin Synthesis: Effecting Control through Chelating Ancillary Ligand Design and Mechanistic Insights

Carrow, B. P.; Nozaki, K.

Macromolecules 2014, 47 (8), 2541-2555.

Pre-Princeton Publications

Synthesis of Functional Polyolefins Using Cationic Bisphosphine Monoxide-Palladium Complexes

Carrow, B. P.; Nozaki, K.

J. Am. Chem. Soc. 2012, 134 (21), 8802-8805.

P-Chiral Phosphine-Sulfonate/Palladium-Catalyzed Asymmetric Copolymerization of Vinyl Acetate with Carbon Monoxide

Nakamura, A.; Kageyama, T.; Goto, H.; Carrow, B. P.; Ito, S.; Nozaki, K.

J. Am. Chem. Soc. 2012, 134 (30), 12366-12369.

Distinguishing Between Pathways for Transmetalation in Suzuki-Miyaura Reactions

Carrow, B. P.; Hartwig, J. F.

J. Am. Chem. Soc. 2011, 133 (7), 2116-2119.

Ligandless, Anionic, Arylpalladium Halide Intermediates in the Heck Reaction

Carrow, B. P.; Hartwig, J. F.

J. Am. Chem. Soc. 2010, 132 (1), 79-81.

Effect of Ligand Steric Properties and Halide Identity on the Mechanism for Oxidative Addition of Haloarenes to Trialkylphosphine Pd(0) Complexes

Barrios-Landeros, F.; Carrow, B. P.; Hartwig, J. F.

J. Am. Chem. Soc. 2009, 131 (23), 8141-8154.

Autocatalytic oxidative addition of PhBr to Pd((PBu3)-Bu-t)(2) via Pd((PBu3)-Bu-t)(2)(H)(Br)

Barrios-Landeros, F.; Carrow, B. P.; Hartwig, J. F.

J. Am. Chem. Soc. 2008, 130 (18), 5842-5843.

Amorphous highly conjugated chemical-vapor-deposited polymer thin films.”

Senkevich, J. J.; Woods, B. W.; Carrow, B. P.; Geil, R. D.; Rogers, B. R.

Chem. Vapor Depos. 2006, 12 (5), 285-289.

Dehydrohalogenation in alpha-functionalized poly-p-xylylenes

Carrow, B. P.; Bakhrit, H.; Wang, P. I.; Chen, Y. Q.; Senkevich, J. L.

Chem. Vapor Depos. 2006, 12 (4), 239-244.

Thermal and dielectric stability of parylene X

Senkevich, J. J.; Carrow, B.; Wang, P.-I.

Mater. Res. Soc. Symp. Proc. 2006, 914, 101–106.

Evaluation of a novel Cu(I) precursor for chemical vapor deposition

Ye, D. X.; Carrow, B.; Pimanpang, S.; Bakhru, H.; Ten Eyck, G. A.; Wang, G. C.; Lu, T. M.

Electrochem. Solid St. 2005, 8 (7), C85–C88.

Poly(ethynyl-p-xylylene), an advanced molecular caulk CVD polymer

Carrow, B. P.; Murray, R. E.; Woods, B. W.; Senkevich, J. J.

Mater. Res. Soc. Symp. Proc. 2005, 863, 189–194.